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  C5/C6 Isomerization ProcessingÀÇ ¸ñÀû°ú Octane
  ±Û¾´ÀÌ : IRRRR   °íÀ¯ID : GPEM     ³¯Â¥ : 13-06-11 14:49     Á¶È¸ : 4274    
<±Û ÇÏ´Ü¿¡ Naphtha Isomerazation ÇÁ·Î¼¼½Ì°ú °ü·ÃÇÏ¿©,
UOP »çÀÌÆ®(http://www.uop.com/processing-solutions/refining/gasoline/#naphtha-isomerization)¿¡¼­ ¹ßÃéÇÑ ¹®ÀåÀ» ÷ºÎÇÕ´Ï´Ù.>
 
Âü°í·Î, º»ÀÎÀº È­ÇаøÇаú Ãâ½ÅÀº ¾Æ´Õ´Ï´Ù.
±Ã±ÝÇÑ Á¡ÀÔ´Ï´Ù.
 
1. C5/C6 Isomerization ProcessingÀÇ Á¤È®ÇÑ ¸ñÀûÀº ¹«¾ùÀԴϱî.
   (º» ÇÁ·Î¼¼½ÌÀ» ÅëÇØ ¾ò´Â ÁÖ »ý»ê¹°ÀÌ GasolineÀε¥, È­ÇнÄÀº °°°í ±¸Á¶½ÄÀÌ ´Ù¸¥ À̼ºÁúÈ­°¡ GasolineÀ» ¾ò´Â°Í°ú ¾î¶² ¿¬°ü¼ºÀÌ ÀÖ´ÂÁö ¸ð¸£°Ú½À´Ï´Ù.)   
2. C5/C6 Isomerization ProcessingÀ» ÅëÇØ Octane(C8)À» ³ôÀÏ ¼ö ÀÖ´Ù´Â °ÍÀº, Benzene Á¦°Å³ª DIH/DIP µîÀÇ Processing°ú ÇÔ²² Çϱ⠶§¹®ÀÎÁö¿ä.
ȤÀº, C5/C6 Isomerization Processing ÀÚü¸¸À» ÅëÇؼ­µµ high OctaneÀÌ »ý¼ºµÈ´Ù´Â °ÍÀԴϱî.
 
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Today, UOP remains at the forefront of this technology, offering a broad range of processing options for light naphtha (C5/C6) including upgrading of low octane streams and elimination of benzene.
 
We offer two Isomerization options to meet your needs. The UOP Penex¢â process and the UOP Par-Isom¢â process are fixed-bed processes that improve the octane of C5/C6 streams by isomerizing normal components to branched components using UOP¡¯s high-activity catalysts. The reaction conditions promote isomerization and minimize hydrocracking.
These processes are capable of saturating Benzene and can be incorporated into a variety of processing schemes to upgrade low octane C5/C6 streams to products with octane ranging from 80 RONC up to 93 RONC. There are three common options:
  • Hydrocarbon Once-through – the light naphtha passes through the isomerization reactor only once. Normal paraffins are converted to iso paraffins but the conversion is limited by equilibrium. Typical product octanes are in the 80-84 RONC range.
  • Isomerization/DIH – A de-isohexanizer is used to recover and recycle unconverted normal hexane and low octane hexane isomers to the reactor system. RONC values of 87-89 can be achieved.
  • DIP/Isomerization/Super DIH – Using a de-isopentanizer upstream of the Isomerization reactor to remove isopentane and a de-ioshexanizer downstream to recover and recycle low octane hexanes, RONC values of 90-93 can be achieved.

½ºÅ×Æijë Stefano   13-06-12 11:53
(A1) Áú¹®°ú °ü·ÃµÈ ³»¿ëÀº Á¤À¯°øÀå À¯ºÐÁß ºñ±³Àû ÀúºñÁ¡À» °¡Áö´Â Ææź ¹× Çí»ê ¼ººÐÀ» "À̼ºÈ­"°úÁ¤À¸·Î ó¸®ÇÏ¿© "°í¿Áź°¡"¸¦ °¡Áö´Â °í±Þ°¡¼Ö¸°À» »ý»êÇϴµ¥ »ç¿ëÇÏ´Â ¹æ¹ý¿¡ °üÇÑ °ÍÀÔ´Ï´Ù. 

<C5/C6 Isomerization ProcessingÀÇ Á¤È®ÇÑ ¸ñÀû>Àº  Á÷¼±±¸Á¶¸¦ °¡Áö´Â n-ÆæźÀ̳ª n-Çí»êÀ» °ç°¡Áö¸¦ °¡Áö°í ÀÖ´Â IsoÆæźÀ̳ª IsoÇí»êÀ¸·Î ±¸Á¶º¯°æÇÔÀ¸·Î½á  ¿Áź°¡°¡ ³ôÀº ¼ººÐÀ¸·Î ¹Ù²Ù¾î ÁÖ±â À§ÇÔÀÔ´Ï´Ù. ÆæźÀ̼ºÃ¼µéÀÇ ±¸Á¶´Â  http://en.wikipedia.org/wiki/Pentane ¿¡¼­ ã¾Æº¼¼ö Àִµ¥ normal-Pentane(n-C5)º¸´Ù iso-pentane(i-C5)ÀÇ ¿Áź°¡°¡ ³ô½À´Ï´Ù. 

(¿Áź°¡°¡ ³·À¸¸é ³»¿¬±â°üÀÇ È¥ÇÕ°¡½º ¾ÐÃà°úÁ¤¿¡¼­ Á¡È­¸¦ ÇÏÁö ¾Ê¾Æµµ ¿¬¼ÒµÇ¾î ¿£Áø¿¡¼­ ¼ÒÀ½(" knocking")À» ÀÏÀ¸Å°°í ¿£ÁøÈ¿À²µµ ¶³¾î¶ß¸³´Ï´Ù.  ¿Áź°¡¸¦ Á¤·®ÀûÀ¸·Î Æò°¡ÇÏ´Â ¹æ¹ýÀº RON(ASTM D-908)ȤÀº MON (ASTM D-357)ÀÇ ¹æ¹ýÀÌ Àִµ¥ ÀοëÇÑ Site¿¡¼­´Â RON ¼öÄ¡·Î ¼³¸íÇÏ°í ÀÖ½À´Ï´Ù.)   

(A2) ¾Õ¼± ¼³¸í°ú °°ÀÌ C5/C6 IsomerizationÀº À̼ºÁúü º¯°æ(À̼ºÈ­ Isomerization) ¹ÝÀÀ±â¸¦ Åë°ú½ÃÄÑ n-C5/n-C6 ¼ººÐµéÀ» °¢°¢ i-C5/i-C6 ¼ººÐÀ¸·Î ±¸Á¶º¯°æÇØ ÁÖ´Â °úÁ¤Àε¥ ÈÄÀÚÀÇ ¼ººÐÇÔ·®ÀÌ ³ôÀº, Áï ¿Áź°¡°¡ ³ô¾ÆÁø Á¦Ç°À» Á¦Á¶ÇÏ´Â °øÁ¤ÀÔ´Ï´Ù. 

DIP/DIH´Â À̼ºÈ­ ¹ÝÀÀ±â¸¦ Åë°úÇÑ »ý¼ºµÈ  i-C5/i-C6 ¼ººÐµéÀ» ºÐ¸®ÇÏ°í ¹Ì¹ÝÀÀµÈ n-C5/n-C6 ¼ººÐÀ» ´Ù½Ã ¹ÝÀÀ±â·Î ¼øȯ½ÃÅ°±â À§ÇØ »ç¿ëÇÏ´Â ºÐ¸®Å¾µéÀ» ¸»ÇÕ´Ï´Ù.  ºÐ¸®°úÁ¤¿¡¼­  i-C5/i-C6 ¼ººÐµéÀÌ Å¾ »óºÎ·Î À¯ÃâµÇ¾î »ý»êµÇ°í ÀüȯµÇÁö ¾ÊÀº ¹Ì¹ÝÀÀ  n-C5/n-C6 ÀÌ Å¾ Áß°£¿¡¼­ »Ì¾Æ ¹ÝÀÀ±â·Î ¼øȯµÇ°í , ±×¸®°í °íºñÁ¡ ¼ººÐ¹°ÁúÀÎ C7+¼ººÐÀÌ Å¾ÀÇ ÇϺηΠ¹èÃâµÇ¾î »ý»êµË´Ï´Ù.

°øÁ¤±â¼úÀ» º¸À¯ÇÑ È¸»ç´Â C5(ȤÀº C6) IsomerizationÀº  ¹ÝÀÀ±â¸¸ µÎ°í DIP(ȤÀº DIH)¸¦ µÎÁö ¾Ê´Â Once-thru °øÁ¤À» »ç¿ëÇϰųª  C5(ȤÀºC6) Isomerization  ¹ÝÀÀ±â¿Í  DIP(ȤÀº DIH)¸¦ ÇÔ²² µÐ Recycle Stream °øÁ¤À» Á¦¾ÈÇÏ°í ÀÖ½À´Ï´Ù. 

ÀüÀÚÀÇ °æ¿ì ¸¸À¸·Îµµ Octane°¡¸¦ ³ôÀÏ ¼ö ÀÖÁö¸¸  ÈÄÀÚÀÇ °æ¿ì´Â ¹Ì¹ÝÀÀµÈ ¹°ÁúÀ» ´Ù½Ã ¼øȯ½ÃÄÑ ¹ÝÀÀÇϱ⠶§¹®¿¡ ´õ ³ôÀº ³óµµÀÇ  i-C5(ȤÀº i-C6)¸¦ ¾òÀ» ¼ö ÀÖ½À´Ï´Ù.  ±×·¯³ª Á¤À¯°øÀå »ý»ê GasolineÁ¦Ç°Àº ´Ü¼øÈ÷ C5, C6µî ¸¸ÀÇ ¼ººÐ¸¸À¸·Î ÀÌ·ç¾îÁø °ÍÀÌ ¾Æ´Ï°í ¿©·¯ À¯ºÐÀ» ¼¯¾î¼­ Á¦Á¶Çϱ⠶§¹®¿¡ ÇÊ¿ä¿¡ µû¶ó Isomerizer¸¸ µÎ°Å³ª Isermer¿Í ºÐ¸®Å¾ÀÇ Á¶ÇÕÀ» ÅÃÇÏ¸é µÉ °ÍÀÔ´Ï´Ù.

(A3) Isoemer ¹ÝÀÀ±â¿¡¼­´Â Ã˸Ż󿡼­ ¼ö¼Ò¿Í ¹ÝÀÀ½ÃÄÑ normal paraffins¸¦ isomer·Î Àüȯ½ÃÅ°±âµµ ÇÏÁö¸¸ BenzeneÀÇ Hydrogenationµµ ÇÔ²² ÀϾ  Benzene-->CyclohehaneÀ¸·Î ÀüȯµÈ ÈÄ ¹ÝÀÀ»ý¼º¹°Àº ¸ðµÎ DIP/DIH Áõ·ù°øÁ¤¿¡¼­ ºÐ¸®, »ý»êµÈ´Ù´Â °ÍÀ» ¼³¸íÇÏ°í ÀÖ½À´Ï´Ù.
     
IRRRR GPEM   13-11-06 13:54
»ó¼¼ÇÑ ¼³¸í °¨»çÇÕ´Ï´Ù.
   

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