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End to end distance of a polymer chain is given as
 
                     1 + cos(180 - t )            1 + <cos %>
<r^2> = nl^2  ------------------- X ------------------
                     1 - cos(180 - t )            1 - <cos %>
 
          <cos%> = origin of temperature dependence
 
For polyethylene, degree of polymerication = 10000, bond angle = 110 degree.
Half of the conformation are T and the other half G(or G').
 
1. Calculate the <r^2>
2. What happens to <cos%> as temperature increase?
 
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½ºÅ×Æijë Stefano   12-10-16 20:34
(1) <r^2>ÀÌ¸é ±æÀÌÀÇ Á¦°ö°ªÀ» ±¸Ç϶ó´Â °ÍÀ¸·Î º¸ÀÌ°í  °è»êÀº ÁÖ¾îÁø °ªÀ¸·Î °è»êÇÏ¸é µÉ ÅÍÀÌÁö¸¸, ÀοëÇÑ ¼ö½ÄÀÇ À¯·¡¿Í ÀǹÌÇÏ´Â ¹Ù´Â ±³°ú¼­¿¡¼­ ã¾Æ º¸°Å³ª ±³¼ö´Ô²² ¹®ÀÇÇÒ ¼ö ¹Û¿¡ ´Ù¸¥ µµ¿ò¹Þ±â ¾î·Á¿ö º¸ÀÔ´Ï´Ù. 

(2) µÎ¹ø° Áú¹®¿¡¼­´Â <cos %>°ªÀÌ Ä¿Áö¸é ºÐ¸ð°¡ ÁÙ°í ºÐÀÚ°¡ ´Ã¾î³ª´Ï±î <r^2>µµ Å©°Ô Áõ°¡ÇÒ °ÍÀ¸·Î º¾´Ï´Ù.

(3) °¢ ±âÈ£ÀÇ Àǹ̴ ¾ð¶æ º¸±â¿¡ nl = ÁßÇÕµµ t = °áÇÕ°¢µµ, <r^2> = end-to-end distance of Polymer Chain °ªÀÇ Á¦°öÄ¡ ·Î º¸À̴µ¥ °ú¿¬ ÀÌ ¸»ÀÌ ¸Â´ÂÁö´Â ½º½º·Î ¾Ë¾Æº¸¼¼¿ä. 
   

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