ÀÚµ¿·Î±×ÀÎ
ÄÁÅÙÃ÷ | contents
ÀϹݰԽÃÆÇ
Q&A°Ô½ÃÆÇ
°øÇÐ S/W
½ºÅ͵ð | study
´ÜÀ§È¯»ê
³óµµ°è»ê
ÀϹÝÈ­ÇÐ
È­°øÀϹÝ
È­°ø½Ç¹«

   
  ½ºÅ×Æijë´Ô Çѹø ºÁÁÖ¼¼¿ä
  ±Û¾´ÀÌ : karls   °íÀ¯ID : skdcjss     ³¯Â¥ : 08-03-31 22:40     Á¶È¸ : 5991    
¾Æ·¡ ¿Ã¸° ¹®Á¦¿¡ ¿ø¹®À» ¿Ã¸®´Ï Çѹø ºÁÁֽñ⠹ٶø´Ï´Ù.
¹ø°Å·Ó°Ô Çصå·Á ÁË¼Û Çϳ׿ä.
 
A stream contains a waste chemical, W, with a concentration of 1 mol/liter. To meet Environmental Protection Agency and state standards, at least 90% of the chemical must be removed by reaction.
The chemical decomposes by a second-order reaction with a rate constant of 1.5 liter/(mol hr). The stream flow rate is 100 liter/hour and two available reactors (400 and 2000 liters ) have been placed in series (the smaller reactor is placed before the larger one).
 
a. Write the modeling equations for the concentration of the waste chemical.
    Assume constant volume and constant density. Let
 
  C_w1 = concentration in reactor 1, mol/liter
  C_w2 = concentration in reactor 2, mol/liter
  F   = volumetric flow rate, liter/hr
  V_1 = liquid volume in reactor 1, liters
  V_2 = liquid volume in reactor 2, liters
   k = second-order rate constant, liter/(mol hr)

½ºÅ×Æijë Stefano   08-04-01 19:41
(1) Á¤»ó»óÅ¿¡¼­ÀÇ CSTR¿¡¼­ÀÇ ¹°Áú¼öÁö¸¦  ³ªÅ¸³»¸é
(Input)-(Output)+(Generation)=(Accumulation) = 0  ..........................(1)  ¡ñSteady State

(2) 2Â÷¹ÝÀÀ½ÄÀÇ ¹ÝÀÀ¼Óµµ¼ö½ÄÀÌ ´ÙÀ½°ú °°´Ù¸é (C=C1 or C2)
-rw = k C^2...................................................................................(2)  -rw = WÀÇ ¼Ò¸ê¼Óµµ

(3) À§ ¹°Áú¼öÁö¿Í ¹ÝÀÀ¼Óµµ¼ö½ÄÀ» µÎ°³ÀÇ ¹ÝÀÀ±â¿¡ ´ëÇØ ´ëÀÔÇϸé

1st Reactor:  vCo-vC1+rw*V1 = 0  .............(3a)            vCo-vC1+(V1*k)C1^2=0............(4a)
2nd Reactor:  vC1-vC2+rw*V2 = 0...............(3b)            vC1-vC2+(V2*k)C2^2=0............(4a)

À§ÀÇ (4a), (4b) ¼ö½ÄÀº °¢°¢ C1, C2ÀÇ 2Â÷ÇÔ¼ö·Î ³ªÅ¸³ª Àִµ¥ À̷κÎÅÍ C1, C2¸¦ ±¸Çغ¸¸é °¢ ¹ÝÀÀ±âÀÇ Ãⱸ¿¡¼­ÀÇ ³óµµ¸¦ ±¸ÇÒ ¼ö ÀÖ½À´Ï´Ù.  (2Â÷¹æÁ¤½ÄÀÇ ±ÙÀ» ±¸ÇØ¾ß ÇÏ°Ú½À´Ï´Ù. )

(4) 2nd Reactor Ãⱸ¿¡¼­ÀÇ ³óµµ
C2 °ªÀ»  (4b)½ÄÀÇ ±Ù ±¸Çϱ⠹æ¹ýÀ¸·Î ±¸ÇÑ ´ÙÀ½ ¿©±â¿¡ C1À»  (4a)½Ä¿¡¼­ À¯È¿ÇÑ °ªÀ» ³Ö¾îÁÖ¸é µÉ °ÍÀÔ´Ï´Ù.
(µÎ°³ÀÇ 2Â÷¹æÁ¤½Ä¿¡¼­ÀÇ ±ÙÀº  À½¼ö°¡ ³ª¿ÀÁö ¾Ê´Â °ªÀ» °¢°¢ ÅÃÇÏ¸é µÉ °ÍÀÔ´Ï´Ù. ³óµµ´Â À½¼ö°¡ µÉ ¼ö ¾øÀݾƿä.)
   

Copyright 1999.07.10-Now ChemEng.co.kr & 3D System Engineering. (mail : ykjang@naver.com, call 010-4456-8090)